99 Conjugate Variable
A variable paired with another variable through a derivative that is used to replace that other variable in a Legendre transform, where a Legendre transform is a change from velocity variables to momentum variables.
The definition of conjugate momentum. The momentum conjugate to a coordinate \(q_{i}\) is the derivative of the Lagrangian with respect to the corresponding velocity. This principle is used to define \(p_{i}\) from \(L\).
The conjugate momentum is
\[ p_{i} = \dfrac{\partial L}{\partial\!\left(\dfrac{dq_{i}}{dt}\right)} \]
where
- \(L\) is the Lagrangian.
- \(q_{i}\) is the \(i\)-th generalized coordinate.
- \(\dfrac{dq_{i}}{dt}\) is the \(i\)-th generalized velocity.
- \(p_{i}\) is the momentum conjugate to \(q_{i}\).
Conjugate pairs. A coordinate and its conjugate momentum form a conjugate pair. Position and momentum are the standard example. This principle is used to label phase-space coordinates \((q,p)\).
The canonical commutation relation. In quantum mechanics a conjugate pair does not commute. This principle is used to write the canonical commutation relation and the uncertainty principle.
The canonical commutation relation is
\[ [\hat{q},\hat{p}] = i\hbar \]
where
- \(\hat{q}\) is the position operator.
- \(\hat{p}\) is the momentum operator.
- \(\hbar\) is the reduced Planck constant.
Note: Also called a canonically conjugate variable. Also called conjugate momentum when paired with a coordinate.
99.1 References
- Cahill, K. Physical Mathematics. Cambridge University Press, 2019. — \(p_{i}=\partial L/\partial(\mathrm{d}q_{i}/\mathrm{d}t)\) as momentum canonically conjugate to \(q_{i}\).
- Park, D. Introduction to the Quantum Theory. Dover, 2005. — coordinates and momenta are conjugate to each other.
- Sakurai, J. J., & Napolitano, J. Modern Quantum Mechanics. Cambridge University Press, 2021. — \([x,p]=i\hbar\).
- Absorption
- Angular Momentum
- Atomic Orbitals
- Aufbau Principle
- Bohr Radius
- Bra and Ket
- Commutators
- Conjugate Variable
- Conservation Laws
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- de Broglie Wavelength
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