149 Superposition
A linearity principle that is used to write a quantum state as a sum of allowed states, where a linear combination is a sum with complex coefficients.
Linear combination of states. If \(|\psi\rangle\) and \(|\phi\rangle\) are allowed states, then \(a|\psi\rangle+b|\phi\rangle\) is an allowed state. This principle is used to build interference and to expand a state in a basis.
The superposition of two states is
\[ |\Psi\rangle = a|\psi\rangle + b|\phi\rangle \]
where
- \(|\Psi\rangle\) is the superposed state.
- \(a\) and \(b\) are complex coefficients.
- \(|\psi\rangle\) and \(|\phi\rangle\) are the component states.
Linearity of the Schrödinger equation. The Schrödinger equation is linear, so a sum of solutions is a solution. This principle is used to write the general time-dependent solution as a sum of stationary states.
Born probabilities of expansion coefficients. The probability of an outcome is the squared modulus of the corresponding coefficient, not the sum of the separate probabilities, when the components can interfere. This principle is used to compute two-slit and spin-superposition probabilities.
The Born probability of a basis outcome is
\[ P(n) = \lvert c_{n}\rvert^{2} \]
where
- \(P(n)\) is the probability of outcome \(n\).
- \(c_{n}\) is the coefficient of \(|n\rangle\).
149.1 References
- Sakurai, J. J., & Napolitano, J. Modern Quantum Mechanics. Cambridge University Press, 2021. — superposition of kets.
- Griffiths, D. J. Introduction to Quantum Mechanics. Cambridge University Press, 2018. — linear superposition of wavefunctions.
- Absorption
- Angular Momentum
- Atomic Orbitals
- Aufbau Principle
- Bohr Radius
- Bra and Ket
- Commutators
- Conjugate Variable
- Conservation Laws
- Conservation of Angular Momentum
- Conservation of Charge
- Conservation of Energy
- Conservation of Energy Transition Law
- Conservation of Momentum
- de Broglie Wavelength
- Derivation of Hamiltonian
- Derivation of Lagrangian
- Dipole Selection Rules
- Eigenvalue
- Eigenvector
- Einstein Coefficients
- Electromagnetic Interaction
- Electromagnetic Interaction
- Electromagnetic Radiation
- Electron Configurations
- Energy Quantization
- Expectation Values
- Fermi’s Golden Rule
- Hamiltonian
- Hund’s Rule
- Hydrogen Energy Levels
- Lagrangian
- Magnetic Moment
- Measurement
- Momentum Operator
- Normalization
- Operators
- Orbital Angular Momentum
- Pauli Exclusion Principle
- Photon Momentum
- Planck Relation
- Position Operator
- Potential Wells
- Probability Current
- Probability Density
- Quantum Harmonic Oscillator
- Quantum States
- Quantum Tunneling
- Rydberg Formula
- Scattering Theory
- Schrodinger Equation Time-Independent
- Schrodinger Equations
- Selection Rules
- Spin
- Spin-Orbit Coupling
- Spontaneous Emission
- Stimulated Emission
- Superposition
- Time Dependent Schrodinger Equation 1-Dimensional
- Time Dependent Schrodinger Equation Generalized
- Total Angular Momentum
- Uncertainty Principle
- Wave-Particle Duality
- Wavefunctions