107 Derivation of Hamiltonian
A derivation of the Hamiltonian that is used to obtain \(H(p,q)=\displaystyle\sum_{i}p_{i}\dfrac{dq_{i}}{dt}-L\) from the Lagrangian by a Legendre transform, where a Legendre transform is a change from velocity variables to momentum variables.
1. Start from a Lagrangian that depends on position and velocity. This principle is used to treat \(H\) as the Legendre transform of \(L\).
The Lagrangian is
\[ L = L\left(q,\dfrac{dq}{dt}\right) \]
where
- \(L\) is the Lagrangian.
- \(q\) is a generalized coordinate.
- \(\dfrac{dq}{dt}\) is the generalized velocity.
2. The conjugate momentum is the slope of \(L\) in velocity. This principle is used to introduce \(p\) as the new independent variable.
The conjugate momentum is
\[ p = \dfrac{\partial L}{\partial \left(\dfrac{dq}{dt}\right)} \]
where
- \(p\) is the conjugate momentum.
- \(L\) is the Lagrangian.
3. The Hamiltonian is \(p\) times velocity minus \(L\), with velocity expressed in terms of \(p\). This principle is used to write \(H\) as a function of \(p\) and \(q\) alone.
The Hamiltonian is
\[ H(p,q) = p\,\dfrac{dq}{dt}(p) - L\left(q,\dfrac{dq}{dt}(p)\right) \]
where
- \(H\) is the Hamiltonian.
- \(p\) is the conjugate momentum.
- \(L\) is the Lagrangian.
4. For \(L=\dfrac{1}{2}m(\mathrm{d}q/\mathrm{d}t)^{2}-U(q)\) one obtains \(H=p^{2}/2m+U(q)\). This principle is used to recover the energy \(T+U\) and the quantum operator \(P^{2}/2m+V(X)\).
The simple Hamiltonian is
\[ H(p,q) = \dfrac{p^{2}}{2m} + U(q) \]
where
- \(m\) is the mass.
- \(U(q)\) is the potential energy.
5. Matching the differential of \(H\) yields Hamilton’s equations. This principle is used to write first-order equations for \(q\) and \(p\).
Hamilton’s equations are
\[ \dfrac{dq_{i}}{dt} = \dfrac{\partial H}{\partial p_{i}},\qquad \dfrac{dp_{i}}{dt} = -\dfrac{\partial H}{\partial q_{i}} \]
where
- \(q_{i}\) is a generalized coordinate.
- \(p_{i}\) is the conjugate momentum.
- \(H\) is the Hamiltonian.
Note: These principles are the Lagrangian starting point, conjugate momentum, the Legendre transform, \(H=T+U\) for a standard kinetic term, and Hamilton’s equations.
107.1 References
- MIT OpenCourseWare. 8.223 Classical Mechanics II, Lecture 15: Introduction to Hamiltonian Mechanics (IAP 2017). — Legendre transform \(H = p\dot{q}-L\), simple case \(H=T+U\), and Hamilton’s equations.
- Absorption
- Angular Momentum
- Atomic Orbitals
- Aufbau Principle
- Bohr Radius
- Bra and Ket
- Commutators
- Conjugate Variable
- Conservation Laws
- Conservation of Angular Momentum
- Conservation of Charge
- Conservation of Energy
- Conservation of Energy Transition Law
- Conservation of Momentum
- de Broglie Wavelength
- Derivation of Hamiltonian
- Derivation of Lagrangian
- Dipole Selection Rules
- Eigenvalue
- Eigenvector
- Einstein Coefficients
- Electromagnetic Interaction
- Electromagnetic Interaction
- Electromagnetic Radiation
- Electron Configurations
- Energy Quantization
- Expectation Values
- Fermi’s Golden Rule
- Hamiltonian
- Hund’s Rule
- Hydrogen Energy Levels
- Lagrangian
- Magnetic Moment
- Measurement
- Momentum Operator
- Normalization
- Operators
- Orbital Angular Momentum
- Pauli Exclusion Principle
- Photon Momentum
- Planck Relation
- Position Operator
- Potential Wells
- Probability Current
- Probability Density
- Quantum Harmonic Oscillator
- Quantum States
- Quantum Tunneling
- Rydberg Formula
- Scattering Theory
- Schrodinger Equation Time-Independent
- Schrodinger Equations
- Selection Rules
- Spin
- Spin-Orbit Coupling
- Spontaneous Emission
- Stimulated Emission
- Superposition
- Time Dependent Schrodinger Equation 1-Dimensional
- Time Dependent Schrodinger Equation Generalized
- Total Angular Momentum
- Uncertainty Principle
- Wave-Particle Duality
- Wavefunctions