138 Quantum States
A complete description of a quantum system that is used to compute the probabilities of every measurement, where a complete description is a wavefunction or a ket that determines all expectation values.
The Hilbert-space state. The state of a system is a vector in a Hilbert space. A Hilbert space is a complete inner-product space of possible states. This principle is used to add states and to compute inner products.
Ray equivalence. Two kets that differ by a nonzero complex factor represent the same physical state. This principle is used to work with normalized representatives.
The position-space wavefunction. The wavefunction \(\Psi(x,t)\) is the position representation of the state. This principle is used to compute position probabilities from \(|\Psi|^{2}\).
Superposition. A general state is a superposition of basis states. A superposition is a linear combination of allowed states. This principle is used to expand a state in the energy basis or the spin basis.
A general expansion is
\[ |\psi\rangle = \sum_{n}c_{n}|n\rangle \]
where
- \(|\psi\rangle\) is the state.
- \(|n\rangle\) are basis states.
- \(c_{n}\) are complex coefficients.
The measurement update. A measurement of an observable yields one eigenvalue and leaves the system in the corresponding eigenstate. This principle is used to connect the abstract state to a laboratory outcome.
138.1 References
- Sakurai, J. J., & Napolitano, J. Modern Quantum Mechanics. Cambridge University Press, 2021. — kets as states.
- Griffiths, D. J. Introduction to Quantum Mechanics. Cambridge University Press, 2018. — wavefunctions as states.
- Absorption
- Angular Momentum
- Atomic Orbitals
- Aufbau Principle
- Bohr Radius
- Bra and Ket
- Commutators
- Conjugate Variable
- Conservation Laws
- Conservation of Angular Momentum
- Conservation of Charge
- Conservation of Energy
- Conservation of Energy Transition Law
- Conservation of Momentum
- de Broglie Wavelength
- Derivation of Hamiltonian
- Derivation of Lagrangian
- Dipole Selection Rules
- Eigenvalue
- Eigenvector
- Einstein Coefficients
- Electromagnetic Interaction
- Electromagnetic Interaction
- Electromagnetic Radiation
- Electron Configurations
- Energy Quantization
- Expectation Values
- Fermi’s Golden Rule
- Hamiltonian
- Hund’s Rule
- Hydrogen Energy Levels
- Lagrangian
- Magnetic Moment
- Measurement
- Momentum Operator
- Normalization
- Operators
- Orbital Angular Momentum
- Pauli Exclusion Principle
- Photon Momentum
- Planck Relation
- Position Operator
- Potential Wells
- Probability Current
- Probability Density
- Quantum Harmonic Oscillator
- Quantum States
- Quantum Tunneling
- Rydberg Formula
- Scattering Theory
- Schrodinger Equation Time-Independent
- Schrodinger Equations
- Selection Rules
- Spin
- Spin-Orbit Coupling
- Spontaneous Emission
- Stimulated Emission
- Superposition
- Time Dependent Schrodinger Equation 1-Dimensional
- Time Dependent Schrodinger Equation Generalized
- Total Angular Momentum
- Uncertainty Principle
- Wave-Particle Duality
- Wavefunctions